W8BYA,
All pressure vessels have a rated lifetime for a reason, to keep people safe from Rapid Unscheduled Disassembly ( thank you Elon Musk ). There is a date stamped on the side of the 20+ Lb propane cylinders and pressurized air storage tanks to prevent it from being refilled after that date and the 1 Lb bottles are built for single use/ single fill only. That is also why the connection on 20+ Lb bottles has been periodically changed to prevent the continued use of older cylinders.
HF does make a connection that would allow you to fill a 1 Lb bottle but you are playing with a hand grenade that may or may not go off. Air pressure tanks have a valve to remove ( blow off ) water that accumulates so as not to compromise the tank by causing internal pitting/ rusting. 1 Lb cylinders have no means of getting rid of water.
Here is propane vapor pressure graph ( log scale ) but I have no idea what the schrader pressure relief valve on top of the 1 Lb bottle is rated for.
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Here is a possible non exploding solution
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