I've seen many articles that comment on how the bubble insulation r-value isn't accurate. It's really only R-1.5 or so. It works well as the 'outer' layer for a pole barn though as it won't be damaged by water and doesn't support birds or mice nesting in it like fiberglass batts.
Personally, I'd go with the rigid foam board as your second layer. XPS, EPS, and polyiso have different r-values per inch and different characteristics -- if I remember correctly, XPS insulative value degrades over time and polyiso's insulative value declines as temperature drops, but EPS has the lowest R value per inch. I'd verify that, though, as my memory may have jumbled up those details.
Did you exclude batts in the walls for some reason?