"it sounded like a two man job and not sure I want to involve my better half if possible." I can identify; my wife's the "beta tester" in the family - if ANYONE on the planet can find a "bug" in ANYTHING, it's her :laughing:
But, if you were to FIRST build the SHORTEST version of a "power strip" for your cart that you would use, you would have a way to insert meter probes in ONE of the receptacles and your PM45xp in the other - then, any normal DMM could be used for voltage - just check first with NO load, then push the RANGE button to lock it in that range (otherwise it will drive you NUTS trying to read it) - then, take a thicker piece of scrap, set it up for a cut, and with the drag tips it would be easy to start a cut, look away from the torch long enough to read the voltage and you're DONE...
All the cords I mentioned before give me multiple outlets at the 2 locations I normally use for welding stuff so I can plug 2 welders AND the plasma in (at either location) without further extension cords, or in extreme cases I can add the 85 footer with TWO plugs - a simpler way would be a shorter cord with multiple outlets on your cart, then maybe later just a 1 in/1 out extension cord to add in for longer reach.
My reason for the shorter cord is twofold - one, less crap to trip over - two, a bit less voltage drop to add to your already questionable drop for test purposes. But since the NEW cords will hopefully NOT be #10, I would NOT make the multi-outlet cord so short it isn't gonna be usable for your proposed changes in the shop area...
Of course you would STILL have to wire your expanded shop area with enough juice for your needs - I currently (pun intended

) have a 60 amp circuit to the front of my garage, and both "local" area POWER strips run off that - my 5 horse/80 gallon compressor pulls 23 amps running, and I've often been welding at around 200 amps while the compressor's running (same circuit) with no problems at all - 21 CFM at full pressure, then a pre-regulator(my compressor shuts off at 175 psi, pre-regulator set for 110psi)/prefilter/Motorgard - tips last a looooong time with this setup.
Just something to think about... Steve