The air compressor would make sure you had a free flow from the pump through all the valves and back to the tank, which is actually what we want with an open center system.
It won't be able to do much more at only 120 PSI, compared to somewhere around 2500 PSI that the tractor hydraulic system run, so the compressed air won't be able to pushing through the relief valves.
It's still a good test to do, for sure. Just applying pressure on the pressure hose that was connected to the pump.