STOP!!
Before you kill yourself!
I'm not an electrician, nor do I know the latest info in the electric code.
But I do perform a fair amount of electrical work, have installed services and sub panels.
It's hard to tell what you're doing from your original post, or how far your plug is for your RV from your main panel.
BUT NEVER TIE INTO THE MAIN BUS BARS WITH A DIRECT CONNECTED LUG!
You need to install a double pole, 220V breaker made for your service panel.
You can get a GFI breaker, although I'm not sure if they're available in your amp size.
Or you can put a GFI plug for where your RV is going.
BUT YOU NEED TO TAKE OFF YOUR DIRECT CONNECTIONS ON YOUR MAIN BUSSES! THAT ENTIRE WIRE RUN IS UNPROTECTED THAT WAY!
You install a double pole breaker to supply the RV plug, should be 4 conductor wire, black, red, white, bare,(ground).
You already had your panel open, I obviously don't know the manufacturer or model. But your bus bars should look like fingers where the breakers snap in. By putting in a double pole breaker, the breaker should attatch to a 'finger' from each bus bar. Not 2 'fingers' from the same bus.
I don't know what type of wire you've used, if it's aluminum, make sure you use noox on all connections.
If all your outlets in your RV are GFI, you don't really need a GFI breaker or
plug.
You should have 120V at your plug from each hot lead, hot to neutral or hot to ground.
I don't know what kind of volt meter you have, but I would never place lead to terminal, hot to hot on a volt meter.
I hope this helps. If you have no idea what I'm talking about, PLEASE STOP AND GET SOMEONE THAT DOES.