No, that is not how it works at all. Lead sulfide crystals (along with most anything) have a resonance frequency. Hit something at or make it vibrate at that frequency & they shatter. I'm not sure if a DC pulse or AC is used, but it's applied at the resonance frequency of lead sulfide. It takes a while, but it will usually remove the lead sulfide. Desulfating is usually done in combination with a trickle charge.
Hitting a battery with high voltage will boil off electrolyte & kill it. There is a lot of science on what voltage to use at what stage. Higher voltage (14v or so) at the bulk charge stage is fine. 13.5v at the trickle charge maintenance stage could boil it.
The RV BATTERY CHARGING PUZZLE << HandyBob's Blog is a great place to learn about battery charging & solar. A little angry & ranty at times, but he knows his stuff.