Ack!!! Looks like this MSMA stuff may be kinda nasty. Clipped this from a web search:
<font color=blue>Question - The question relates to the potential release of arsenic from the
herbicides MSMA (monosodiummethanearsonate) and cacodylic acid
(dimethylarsinic acid)after they are sprayed on soils. Both compounds
are tightly bound to soils, especially those with high clay content.
However, they are not substantially metabolized in the soil environment
in the absence of microorganisms.
Is the release of arsenic inhibited by the bond strength of the arsenic
to the methyl groups in the molecules? How do these strengths compare
to common compounds such as water, H2O?
---------------------------------------------------------
The following indicates that arsenic in herbicides has been known to cause
soil contamination:
http://www.waite.adelaide.edu.au/Soil_Water/nutrient.html</font color=blue>
Here is another snipet.... be prepared for some mind-numbing language....
<font color=red>The uptake, translocation and metabolism of 14C-MSMA in organic arsenical-resistant and -susceptible Mississippi biotypes of common cocklebur were investigated. The two biotypes did not differ significantly with respect to either uptake, total translocation or translocation pattern of 14C-MSMA plus its radiolabelled metabolites regardless of whether plants were pretreated with 1.12 kg ai ha-1 of unlabelled MSMA or treated only with radiolabelled material. Absorption of 14C-MSMA was greater in unlabelled MSMA-pretreated plants than untreated plants, whereas the percentage of total absorbed 14C-MSMA that was translocated out of the 14C-MSMA-treated leaf was almost the same in MSMA-pretreated and untreated plants. Qualitative detection of 14C-MSMA distribution by autoradiographs confirmed quantitative results obtained with radioassays. Herbicide metabolism in the 14C-treated leaf showed that MSMA was not readily broken down in both biotypes and the extractable 14C was the same. Uptake, translocation and metabolic degradation were not involved in the mechanism of resistance of the resistant-Mississippi biotype common cocklebur to MSMA</font color=red>
I kinda, maybe think that it might say something bad... but then again... it kinda, maybe be something good. Translation please..... /w3tcompact/icons/shocked.gif/w3tcompact/icons/eyes.gif/w3tcompact/icons/laugh.gif
My curiosity is triggered by xxxx-icides. I like to look them up prior to using to make a educated decision. We tend not to use any herbicides or insectisides. Herbicides only in the fringe areas of the property away from our crops and only organic insecticides when absolutely necessary.
I think that the 2-D based herbicides are used also prior to the grass going to seed. You may also want to check into a pre-emergence to see if that helps. However, make sure that none of the herbicides - pre or post emergence affect your mandarins. Check with your local Extension Office, they should be able to assist you.
Good luck.
Terry
Good luck.