I look at it like this: The larger box blade will have a larger "Volume" capacity and possibly more teeth than the smaller box blade.
My opinion:
VOLUME: If your tractor struggles with the 66" box blade when it is filled to capacity, then you may have to stop filling the 66" box blade when it reaches the capacity of the 60" box blade. You'd still be moving the same volume as the 60" box blade, but the 66" will offer extra capacity with other materials that your tractor can handle. (Note: It could be argued that your capacity may be reduced by the weight difference between the two box blades, however small that may be).
TEETH: If the 66" has more teeth than the 60" box blade, you may be restricted to lowering the same number of teeth as the 60" box blade. Again, you really haven't lost anything, but have extra capacity when your tractor can handle it.
My recommendation:
If you are convinced that you tractor can handle the 60" box blade (I would think that it could easily), then get the box blade with the width that will be most useful for you (whichever one that may be).
I have a 60" box blade that I use with my 24hp Kubota, and have occasionally used a friend's 72" box blade with it. I used the 72" mostly for smoothing operations and didn't fill it to full capacity, but the extra width was more useful for the job that I was doing. I would not want the 72" box blade as my primary box blade because the extra width would get in the way more times than it would be useful.
I've never seen a 66" blade...now that may be something I may consider myself...
Kelvin