One of the biggest dangers with oil burners is the dam reset button on the burner. I can't tell you the number of times I've seen burners where people pushed that button 20 times before they called for service. Then, they swear they didn't push it, and since you're now on a 16 hour day, you believe them, only to find a pool of oil in the firebox waiting to vaporize when she fires. That gets nasty real fast.
Also, there are different types of oil burners, ranging from gun burners to pot burners, with Timkin/Torridheat in between. With guns, there are standard guns, and flame retention head guns.
Gas tends to be pretty much straight forward, a burner and a valve, and you can usually reach the valve to shut it off quick when you have to. With the gas valve off, it's hard to have a runaway fire still burning.
It takes a few years for an oil burner apprentice just to see every type of unit, so there aren't a lot of tecks who really know what they are working on. That leadt to a lot of problems too.
Seperate issue, on the CO2 tests, once a burner is set up, there is no necessity to run a Co2 test every year, that's just a money maker. What you're calling a litmus paper test, sounds like a smoke test, where a few puffs of smoke are pumped thru a filter paper that is compared to a gray scale. That wasn't a Co2 test, and the papers only cost 2 cents each.
It sounds like you're being entertained by a money maker teck, instead of getting your burner properly serviced.