Well yes, steam from wood is doable, and has been done for a couple hundred years. Of course, a pile of wood the size of your house would provide you with sufficient power to run the house for a few days, and you'd need to know how to fire the boiler and operate the generator. Bear in mind steam locomotives fueled by wood stopped every 10 miles for a fresh supply of wood, and stern wheelers towed boats full of wood called luggers.
Now, if you want to go to the cutting edge, and substitute freon for water, it is possible to recover waste heat from your stack on a wood stove, and generate a small amount of electricity. You could also make electric by using a dissimilar joint generation system in a fire, to run a transistor radio.
Back in the 1930s, many commercial buildings in Rochester made their own electricity. As RG&E built it's system they offered a chalenge ~ if any building could generate it's own electric cheaper than RG&E sold electricity, RG&E would pay for their coal. Needless to say, RG&E never paid for anyone's coal, and by the end of the decade, nobody made their own electricity.
Power generation is an economy of scale situation, the more you make the cheaper it is to make per unit. While anyone could make his own electricity, most people wouldn't want to live the lifestyle their capability and capacity would sustain.
I've been close to the make it yourself electric business for over 20 years, and seen systems come and go over that time, and to date the big nasty electric company still has the market cornered. Even peak shaving and load shedding isn't economical when the cost of diesel is over 67 cents a gallon, and that figure allows for the increased cost of demand metering from Big Nasty Utility.