there is a huge amount of coatings out there. every product is going to be different, and you need to pay extra attention to manufacture statements. some may want some sort of special chemical put down and then thoroughly washed off, some may require X amount of days for concrete to cure, to needing multi primer like coats to be put down first. again every product out there even products from same manufacture. read the instructions, and if unsure, call manufacture first.
PREP WORK can be a very big thing in how well things work, and not having any blistering or pealing later on down the line.
being that this is a week old, concrete has not has initial "curing" done, ya you might be able to walk on it, but it may take 30 or so days or longer before you can put anything on it. again double check the product instructions and with manufacture.