That pretty much looks like all the ones I have seen. In the pictures you linked to, The two smaller hex heads at the top nearer the input shaft are the relief/high low flow control mechanism. The longer of the two is actually the locking nut for the setscrew to set the relief/changover pressure.
The hose barb is of course the pump inlet. The port opposite without a plug is the controlled/combined output to the control valve. The one with the plug may be an outlet port from the first stage pump.
A dual stage is two pump sections on the same shaft. They run in parallel for higher volume with a low horsepower input from the shaft. The changeover mechanism shifts the output to a single stage when the output pressure reaches a set point(low enough not to overload the engine) or places the stages in series for high pressure output on the available horsepower. A 5-6HP engine couldn't handle the pump in parallel at full rated pressure.
You could probably tap that other port to power another cylinder, but you would probably want a closed center valve so there was only flow out of that port when you were using the valve/cylinder you connect to it.
Unscrew it and see what is behind it.. You could connect up a hose and run it to a bucket and see if you get flow out of it when running
You could also probably add an open center PB capable valve in line between pump and the existing valve to power more cylinders for other functions without messing with tapping an unknown port on the pump.