The fluid in an open center is either flowing or being use. Should not check it.
Do you know the return port pressure ratings?
On most valves, the return port is not designed to handle the high pressure, and most have a limitation or about 500 psi.
Some have done it but most all manufacturers recommend that the return port go to tank.
If you put these valves in series, the second valve may cause the pressure to build up to the relief pressure and that will be reflected back to the return port of the first valve. Could damage the first valve.
A two spool valve could be used here perhaps.
One of the valves should have a relief valve, set to about 50 psi below the pumps max pressure.