1. Try the Prince Hydraulics site. They have some pretty good diagrams.
2. In theory you could have an infinite number of open center valves but they must be in SERIES. An open center valve is just as it's name implies. The inlet port is a direct path to the outlet port. Untill one of the spools diverts flow to a working port, the fluid flows through the valve body relatively unobstructed(all flow, no pressure) so there is no load on the engine powering the system. If you put two valves on a "T", as you try to get work out of one of the valves, nothing will happen as the fluid will just bypass the work through the open center of the other valve.
With 2 valves in series, there will be no alternate path so as you operate one of the spools, there will be no other path but to the cylinder/motor and pressure will build and work will be performed(and a load will be placed on the pump and engine). You will however only really be able to get any work out of one spool at a time. In a system with double acting cylinders or motors, the flow is never really interrupted. As you divert fluid from the inlet port to a cylinder or motor working port, the return from that cylinder or motor is sent to the valve outlet. This fluid heading down stream from the valve being operated could be diverted by another valve. But as the second cylinder or valve starts to perform work(fluid pressure builds), it will put backpressure on the return side of the first cylinder and hydraulically increase the weight it is moving. The first cylinder would move slower and in turn feed fluid from it's return slower causing the second cylinder to also slow down.