Use of brakes for turning (or cutting brakes, as they may be called), is both useful and potentially dangerous...
The dangerous parts first: if you apply brakes unevenly, especially while travelling at any high rate of speed, and you're likely to lose control. Also, if you do it wrong, you stand the potential of damaging your tractor.
The useful parts: Unless you're on glare ice, you need to turn the wheel too. There are two basic turning manuevers to master. First: on slippery surfaces where turning the steering wheel doesn't produce enough turning effect for you (or where you can't keep the tractor pointed straight by using the steering alone), you can use the brakes to help guide your steering. Press the L brake to turn L, and R brake to turn R. If you're on a slippery surface and you crank the wheel over and apply the brake, you can almost pivot in place!
Second: on any surface, if you need to cut a really tight turn (at low speed!), you can cut the wheel over and then apply the inside brake very firmly (L brake for L turn...and so on). This will lock up the inside rear tire for your turn, and cause the tractor to turn very sharply...while dragging a tire. Notes: 1) if you've got a heavy load in the FEL, you're not likely to be able to turn so terribly short anyhow. 2) With loads on the tractor, you're creating a lot of force, especially on the front spindles. Exercise extreme caution. 3) you're going to tear/mark up whatever you're driving on (i.e. don't do this on your nice turf).
Other neato cutting brake tricks: Heavy load in the FEL and not enough counterweight can reduce your traction. If one rear tire is on a slippery surface and the other is on a solid surface, you can apply brakes to the tire on the slippery surface and use it to shift power to the other tire, thereby moving the tractor. Of course, you can use the diff lock as well...but this can be faster/easier/less strenuous on the tractor (especially if you're trying to turn).
The final notes: don't try using cutting brakes with the diff lock on. It defeats the purpose. Be wary of tractors that have automatic responses to applying the brakes (e.g. tractors that automatically engage 4wd when applying brakes). Be cognizant of the loads you're applying to the front axle when using cutting brakes. And again: DO NOT USE CUTTING BRAKES AT HIGH SPEEDS!!!