OK, spaying chemicals properly and in accordance with labeling is why Many States regulate the sales of chemicals. To purchase some chemicals in Bulk the buyer must have completed a study course with Proof of Certification. The broad leaf herbicide 2,4-D is one that is regulated here.
A higher GPM (gallons per minute) pump will increase productivity by allowing more nozzles on the boom with higher GPM delivery per nozzle. As "clemsonfor" stated, concentrate percentage per gallon will determine the speed of application by a GPA (gallons per acre) Conversion. Wetting is critical with herbicides, fertilizers not so much.
Mrs. BurningBushFarm, with a 15 gallon tank and a 1 GPM pump a boom sprayer can be setup, but for spraying any sizable acreage it will take some time to properly apply the chemicals. Smaller orifice nozzles means less fluid dispensed. That and you will be remixing the tank every 15 minutes. TeeJet has the FieldJet 1/4-KLC-5 nozzle which should work for you and be the easiest to setup and learn from. Only one nozzle used.
Spray Guns Valves Teejet Sprayer Tank Centrifugal Banjo Pump Tractor GPS
FieldJet 1/4-KLC-5 nozzle
Spray width 18 feet plus, depending on pressure
1 GPM @ 40psi (21 foot width at 36 inch height)
1/4 inch Male Pipe Threaded (easy to find fittings for hose)
Get your helping husband to mount it somehow.
Not too much cost to begin learning and actual field tests.
FieldJet PDF Document
http://www.teejet.com/media/b8c4cd48-5bfc-417e-874a-2981f94651fc-CAT50-US_LoRes_p035.pdf
I am only trying to promote the value of learning. Done according to the label by not over or under applying a product will save major $$$ in the long run. Plus the satisfaction knowing one tried their best.
Good Luck