If they aren't marked, you can figure it pretty quickly with compressed air.
Start by shutting the tractor off and lowering the lift arms. Then put a pan under the valve block, and remove the three plugs. Now move the lift control lever to full raise. Turn the spool with a screwdriver. It will only turn one way, about a half turn or so and stop. You can find the pressure port by bumping the starter without starting the engine, as oil will exit that port. Or you can start by blowing air into the ports one at a time. With the pressure port, air will go nowhere, but when you release it you will get a blast of oil. With the sump port, air will escape into the transmission housing somewhere. With the power in port the lift arms will pop up. Then you will know which is which. Properly installed loader valves will utilize all three ports.